What are the most toxic textile dyes?

News 2025-04-07

1. Azo Dyes (Containing -N=N- Bonds)

  • Toxicity:
    • Some release carcinogenic aromatic amines (e.g., benzidine, 4-aminobiphenyl) when degraded.
    • Linked to bladder cancer, skin allergies, and mutations.
  • Common Use: Cheap, vibrant colors in cotton, polyester, and leather.
  • Regulations: Banned in the EU (REACH Annex XVII) but still used in some countries.

2. Disperse Dyes (Used on Polyester & Synthetics)

  • Toxicity:
    • Contain allergens and mutagens (e.g., Disperse Orange 1, Disperse Blue 1).
    • Non-biodegradable, accumulating in water bodies.
  • Health Impact: Skin irritation, respiratory issues, and potential hormone disruption.

3. Chrome (Cr⁶⁺) Mordant Dyes (For Wool & Silk)

  • Toxicity:
    • Hexavalent chromium (Cr⁶⁺) is highly carcinogenic and toxic to aquatic life.
    • Causes DNA damage, kidney failure, and lung cancer.
  • Regulations: Restricted under EU REACH but still used in some leather tanning.

4. Sulfur Dyes (For Dark Shades on Cotton)

  • Toxicity:
    • Release sulfides and heavy metals (e.g., lead, mercury) during production.
    • Can form toxic hydrogen sulfide gas in wastewater.
  • Environmental Impact: Pollutes water, harms aquatic ecosystems.

5. Heavy Metal-Based Dyes (Cadmium, Lead, Mercury)

  • Toxicity:
    • Cadmium (Cd): Carcinogenic, damages kidneys and bones.
    • Lead (Pb): Neurotoxic, affects child development.
    • Mercury (Hg): Causes neurological disorders.
  • Common Use: Bright pigments in prints and coatings.

6. Formaldehyde-Releasing Dyes (For Wrinkle Resistance)

  • Toxicity:
    • Releases formaldehyde, a known carcinogen (IARC Group 1).
    • Causes skin burns, asthma, and cancer in workers.
  • Common Use: “Permanent press” fabrics.