Tetramethyl Ethylenediamine

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Category:Paint chemicals   Own Brand:MT  /MOQ:100KG  /From China/  B2B only.

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Introduction

CAS No. 110-18-9

Content 99%

Packing 160kg/drum

Names and Identifiers

Name N,N,N’,N’-Tetramethylethylenediamine
Synonyms Temed
TMEDA
UN2372
Tetrameen
AI3-26631
HSDB 5396
CCRIS 4870
Propamine D
EINECS 203-744-6
(CH3)2NCH2CH2N(CH3)2
temed electrophoresis
Tetramethyldiaminoethane
Four MethylEthylenediaMine
Tetramethylethylenediamine
Tetramethylethylene diamine
1,2-Bis(dimethylamino)ethane
1,2-Di-(dimethylamino)ethane
Tetramethyl ethylene diamine
1,2-Bis-(dimethylamino)ethane
1,2-Bis-(dimethylamino)-ethane
N,N,N’,N’-Tetramethylethanediamine
N,N,N’,N’-Tetramethylethylenediamine
Dimethyl(2-(dimethylamino)ethyl)amine
N,N,N’,N’-tetramethylethane-1,2-diamine
Ethylenediamine, N,N,N’,N’-tetramethyl-
N,N,N’,N’-Tetramethyl-1,2-diaminoethane
N,N,N’,N’-Tetramethyl-1,2-ethanediamine
N,N,N’,N’-tetramethylethane-1,2-diaminium
1,2-Diaminoethane, N,N,N’,N’-tetramethyl-
1,2-Ethanediamine, N,N,N’,N’-tetramethyl-
N1,N1,N2,N2-tetraMethylethane-1,2-diaMine
1,2-EthanediaMine,N1,N1,N2,N2-tetraMethyl-
1,2-Ethanediamine, N1,N1,N2,N2-tetramethyl-
1,2-Di-(dimethylamino)ethane [UN2372] [Flammable liquid]
N,N,N’,N’-Tetramethylethane-1,2-diamine, electrophoresis grade
CAS 110-18-9
EINECS 203-744-6
InChI InChI=1/C6H16N2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3/p+2
InChIKey DMQSHEKGGUOYJS-UHFFFAOYSA-N

110-18-9 – Physico-chemical Properties

Molecular Formula C6H16N2
Molar Mass 116.2
Density 0.775g/mLat 20°C(lit.)
Melting Point −55°C(lit.)
Boling Point 120-122°C(lit.)
Flash Point 50°F
Water Solubility miscible
Solubility H2O: 10mg/mL at20°C, clear, colorless
Vapor Presure 21 hPa (20 °C)
Vapor Density 4 (vs air)
Appearance Liquid
Specific Gravity 0.777 (20/4℃)
Color Clear colorless to slightly yellow
Odor Amine like
Merck 14,9134
BRN 1732991
pKa 10.40, 8.26(at 25℃)
PH 8.0-8.5 (0.1g/l, H2O, 20℃)
Storage Condition Store below +30°C.
Stability Stable. Highly flammable. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides, copper, mercury.
Sensitive Hygroscopic
Explosive Limit 1-9%(V)
Refractive Index n20/D 1.4179(lit.)
Physical and Chemical Properties
Use Used as biochemical reagents, epoxy resin crosslinking agent, is also a quaternary amine compound Intermediate

110-18-9 – Risk and Safety

Risk Codes R11 – Highly Flammable
R20/22 – Harmful by inhalation and if swallowed.
R34 – Causes burns
R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed.
Safety Description S16 – Keep away from sources of ignition.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDs UN 2372 3/PG 2
WGK Germany 1
RTECS KV7175000
FLUKA BRAND F CODES 3-8-10-34
TSCA Yes
HS Code 29212900
Hazard Note Irritant
Hazard Class 3
Packing Group II

110-18-9 – Upstream Downstream Industry

Raw Materials Formic acid

110-18-9 – Reference Information

LogP -0.13 at 20.2℃
Introduction N,N,N’,N’-tetramethylethylenediamine is a colorless transparent liquid, slightly ammonia odor, miscible with water, miscible in most organic solvents such as ethanol, is an important organic intermediate, mainly used as biochemical reagents, epoxy resin crosslinking agent, quaternary amine compounds synthesis intermediates.
preparation A preparation method of N,N,N’,N’-tetramethylethylenediamine catalyst for Direct Catalytic Amination of dimethylethanolamine: including the following steps:(1) weigh about 24.2g of Cu(NO3)2.3H2O, 14.5g Ni(NO3)2.6H2O and 37.5gAl(NO3)3.9H2O are dissolved in deionized water;(2) 18.0g NaOH which can completely precipitate metal ions is weighed as a precipitant, and dissolved with deionized water to a concentration of 2mol/L;(3) in the state of stirring and water bath temperature of 80 ℃, the nitrate solution prepared in step 1) is slowly added dropwise to step 2) in the prepared NaOH solution, until the pH was 8.0;(4) stirring was carried out at this temperature for 4 hours, and then allowed to stand for aging at the above temperature for 12 hours. (5) the aged catalyst is filtered with suction and washed several times with deionized water until the filtrate has a pH of 7.0; The filter cake is then dried for 32 hours; The dried catalyst is ground to a powder, then calcined in muffle furnace at 450 ℃ for 4 hours, prepared catalyst precursor, wherein the weight percentage content of Cu is 28, the weight percentage content of Ni is 11;(6) the calcined catalyst was tabletted and cut to obtain Ni-Cu/Al2O3 (20-40 mesh) 20mL of finished catalyst; 20 ML of the Ni-Cu/Al2O3 catalyst prepared above was filled in a tubular fixed bed reactor, activated by hydrogen at 250 ℃ for 12h, and fed with dimethyl ethanolamine at reaction temperature of 200 ℃ and reaction pressure of 0.2 Mpa, dimethylethanolamine was continuously catalyzed by dimethylamine and hydrogen. The molar ratio of dimethylethanolamine to dimethylamine was 1:2, and the molar ratio of dimethylethanolamine to hydrogen was 1:20. The volumetric space velocity of dimethylethanolamine was 0.5 h-1, the reaction product was continuously discharged from the lower outlet of the reactor, and the liquid product was analyzed by gas chromatography through gas-liquid separation. The conversion of dimethyl ethanolamine was 87.6%, and N,N,N’,N’-tetramethyl ethyl The diamine selectivity was 78.3%.
purpose is a polar aprotic solvent, also used for the preparation of alkenyl alkynides and other organic reagents
biochemical reagents, the water treatment agent is used as a raw material of a quaternary ammonium salt intermediate.
catalysts for biochemical studies, organic synthesis, cross-linked polymerization.
catalysts in the production of polyurethane foams.
used as Biochemical reagent, epoxy resin crosslinking agent, and quaternary amine compound intermediate
used in the preparation of polyacrylamide gel.
TEMED is a tertiary amine group used to catalyze the formation of free radicals by ammonium persulfate or riboflavin. Free radicals will cause the polymerization of acrylamide and N,N’-methylenebisacrylamide to form a gel matrix useful for sieving macromolecules.
category flammable liquid
toxicity grade poisoning
Acute toxicity oral-rat LD50: 1020 mg/kg; Oral-mouse LD50: 630 mg/kg
stimulation data eye-rabbit 0.750 mg severe
flammability hazard characteristics in case of fire, high temperature, oxidant flammable; toxic NOx smoke from combustion
storage and transportation characteristics The warehouse is ventilated and dried at low temperature; Stored separately from oxidants and acids
extinguishing agent dry powder, dry sand, carbon dioxide, foam
spontaneous combustion temperature 145°C

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