PROPYLENE GLYCOL MONOMETHYL ACETATE

Paint chemicals 2025-03-21

Also known as propylene glycol monomethyl ether acetate, molecular formula C6H12O3. colorless hygroscopic liquid with a special odor, is a non-polluting solvent with multi-functional groups. Mainly used as solvent for ink, paint, ink, textile dyes, textile oils, also used as cleaning agent in the production of liquid crystal displays. Flammable, may form explosive vapor/air mixtures above 42°C.

PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE (PGMEA): TECHNICAL DATA SHEET

Category Specifications
Chemical Name Propylene Glycol Monomethyl Ether Acetate
CAS No. 108-65-6
Molecular Formula C₆H₁₂O₃
Appearance Colorless liquid
Odor Mild, ester-like
Boiling Point 146-149°C
Flash Point 47°C (closed cup)
Density (20°C) 0.97 g/cm³
Vapor Pressure (20°C) 0.4 kPa

Key Properties

Property Performance Data
Solubility Miscible with most organic solvents, limited water solubility (4.5 g/100mL)
Evaporation Rate 0.2 (n-butyl acetate = 1)
Purity ≥99.5% (GC)
Refractive Index 1.40-1.41 (20°C)
Autoignition Temp 345°C

Applications

Industry Primary Uses
Coatings High-performance paints, automotive finishes
Electronics Photoresist solvent in semiconductor manufacturing
Inks Flexographic and gravure inks
Cleaning Agents Precision degreaser
Adhesives Solvent for acrylic/polyurethane systems

Safety & Handling

Parameter Requirements
GHS Classification H226, H319, H336
Exposure Limits (OSHA) 100 ppm (TWA)
PPE Gloves, goggles, ventilation
Storage Sealed containers, cool/ventilated area
Fire Fighting Alcohol-resistant foam, CO₂

Environmental Profile

Aspect Data
VOC Content 100%
Biodegradability ~60% (28 days, OECD 301B)
ODP 0
GWP <1 (CO₂ = 1)

Comparison with Alternatives

Property PGMEA Ethyl Lactate Cyclohexanone
Boiling Point (°C) 146-149 154 156
Flash Point (°C) 47 46 44
Evaporation Rate 0.2 0.3 0.5
Semiconductor Use ★★★★★ ★★★ ★★★★

References:

  1. Handbook of Solvents (3rd Ed.) – George Wypych
  2. SEMI C34 – PGMEA Specifications for Electronics