POLYVINYL ALCOHOL CAS Number: 9002-89-5

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Introduction

CAS Number: 9002-89-5

Polyvinyl alcohol (PVA), a white/yellowish granule or powder, is a stable, non-toxic, and water-soluble polymer. PVA possesses good film-forming property, and the film formed from it has excellent adhesion, solvent-resistance, abrasion-resistance, high tensile strength, and great oxygen barrier property. Due to PVA possesses both hydrophilic and hydrophobic functional groups, it can act as surfactant, and can be used as a protective colloid in polymer emulsification and suspension polymerization.

9002-89-5 – Names and Identifiers

Name Poly(vinyl alcohol)
Synonyms PVA
MOWIOL 4-88
Polyvinyl alcohol
Poly(vinyl alcohol)
POLYVINYLIC ALCOHOL
Polyvinyl alcohol film
POLYVINYL ALCOHOL 2000
polyvinyl alcohol 3-98
poly(1-hydroxyethylene)
polyvinyl alcohol 49000
polyvinyl alcohol 72000
polyvinyl alcohol 18-88
polyvinyl alcohol 15000
polyvinyl alcohol 22000
POLYVINYL ALCOHOL (PVA)
polyvinyl alcohol 28-99
polyvinyl alcohol 100000
Polyvinyl alcohol 1750±50
Vinyl alcohol – polymerised
Polyvinyl alcohol (Release agent)
polyvinyl alcohol standard 200000
CAS 9002-89-5
EINECS 209-183-3

9002-89-5 – Physico-chemical Properties

Molecular Formula C2H4O
Molar Mass 44.05256
Density 1.080 g/cm3
Melting Point >300°C
Boling Point -14.5°C (rough estimate)
Flash Point 79°C
Water Solubility soluble in hot water
Solubility H2O: soluble (hot)
Appearance White or milky white solid
Color White to cream
Merck 14,7585
PH 3.5-7.0 (40g/l, H2O, 20℃)
Storage Condition Store below +30°C.
Stability Stable. Combustible. Dust may form explosive mixtures with air. Incompatible with strong oxidizing agents.
Sensitive Easily absorbing moisture
Refractive Index 1.3810 (estimate)
MDL MFCD00081922
Physical and Chemical Properties White to cream-colored granules or powder
Use Used as warp size, emulsion stabilizer, rewet adhesive, water-soluble film, etc

9002-89-5 – Risk and Safety

Hazard Symbols Xn – Harmful
Risk Codes R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed.
R36/38 – Irritating to eyes and skin.
R39/23/24/25 –
R68/20/21/22 –
R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed.
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 – Wear suitable protective clothing and gloves.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S24/25 – Avoid contact with skin and eyes.
WGK Germany 1
RTECS TR8100000
TSCA Yes
HS Code 39053000
Toxicity LD50 orally in Rabbit: > 20000 mg/kg

9002-89-5 – Upstream Downstream Industry

Raw Materials Acetic acid
Methyl alcohol
Methyl alcohol
2,2′-Azobis(2-methylpropionitrile)
2,2′-Azobis(2-methylpropionitrile)
acetylene
n-Propyl acetate
n-Propyl acetate
Downstream Products Poly(vinyl acetate)

 

 Item  Description
 Name  Polyvinyl Alcohol (PVA)
 Chemical Formula  (C₂H₄O)n
 Appearance  White powder or colorless film
 Solubility  Soluble in water, insoluble in organic solvents such as acetone and toluene
 Molecular Weight  Varies based on degree of polymerization; typically ranges from 30.000 to 100.000 g/mol
 Melting Point  Around 225-235°C (decomposes before melting)
 Density  Approximately 1.19-1.31 g/cm³
 Functionality  Highly versatile polymer used in various industries due to its adhesive, film-forming, and emulsifying properties
 Production Method  Produced through the hydrolysis of polyvinyl acetate under controlled conditions
 Degree of Hydrolysis  Typically ranges from 80% to 99.9%, affecting properties like water solubility and crystallinity
 Applications  Used in textile sizing, paper coating, adhesives, films for packaging, and as a dispersant in ceramic processing
 Environmental Properties  Biodegradable under certain conditions; often preferred over non-biodegradable alternatives
 Safety  Generally recognized as safe (GRAS) by FDA for specific applications; low toxicity
 Advantages  Excellent film-forming ability, good tensile strength, high oxygen barrier property, and eco-friendly nature
 Disadvantages  Limited solvent resistance, sensitive to moisture, and requires careful handling during storage to prevent degradation
 Key Manufacturers  Companies like Kuraray, Celanese, and Shin-Etsu are leading producers globally

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