POLYTETRAMETHYLENE ETHER GLYCOL

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Introduction

Poly(tetramethylene ether)glycol is a product obtained from the polymerization reaction catalyzed by THF under acid catalyst, and it is a chained bisol with tetramethylene ether repeating connection.

Names and Identifiers

Name terathane(R) 1400
Synonyms PTMG
b2000
PTMEG
polifurit
hiprenemc532
Terathane 1400
terathane(R) 1400
poly(butyleneoxide)
Poly(tetrahydrofuran)
(2S)-2-butoxybutan-1-ol
glycols,polytetramethylene
poly(oxy-1,4-butylene)glycol
alpha-hydro-omega-hydroxy-poly(oxy-4-butanediyl)
terathane 2000 polyether glycol (poly-tetrahydrof
4-butanediyl),.alpha.-hydro-.omega.-hydroxy-poly(oxy-1
CAS 25190-06-1
EINECS 607-637-9
InChI InChI=1/C8H18O2/c1-3-5-6-10-8(4-2)7-9/h8-9H,3-7H2,1-2H3/t8-/m0/s1

25190-06-1 – Physico-chemical Properties

Molecular Formula C16H33O5X2
Molar Mass 305.43
Density 1g/mLat 25°C
Melting Point 33-36°C
Boling Point 195.7°C at 760 mmHg
Flash Point >230°F
Vapor Presure <0.01 mm Hg ( 25 °C)
Specific Gravity 0.961
PH 7 (H2O, 20℃)Aqueous solution
Storage Condition Store below +30°C.
Refractive Index n20/D 1.465
Physical and Chemical Properties Polytetrahydrofuran is a white waxy solid that dissolves readily in alcohols, esters, ketones, aromatic hydrocarbons, and chlorinated hydrocarbons, and is insoluble in ester hydrocarbons and water, and becomes a transparent liquid when the temperature exceeds room temperature.

25190-06-1 – Risk and Safety

Hazard Symbols Xi – Irritant
Risk Codes 36/37/38 – Irritating to eyes, respiratory system and skin.
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 – Wear suitable protective clothing.
WGK Germany 1
RTECS MD0916000
HS Code 3907 20 20
Toxicity LD50 orally in Rabbit: > 5000 mg/kg

POLYTETRAMETHYLENE ETHER GLYCOL (PTMEG): TECHNICAL DATA SHEET

Category Specifications
Chemical Name Polytetramethylene Ether Glycol
CAS No. 25190-06-1
Molecular Formula HO-(CH₂CH₂CH₂CH₂O)ₙ-H
Appearance Colorless to pale yellow viscous liquid
Molecular Weight 650-3000 g/mol (customizable)
Hydroxyl Value 28-112 mg KOH/g
Viscosity (40°C) 50-3000 mPa·s

Key Properties

Property Performance Data
Thermal Stability Stable up to 200°C
Hydrolysis Resistance Excellent (pH 4-9)
Low-Temperature Flexibility Retains elasticity below -50°C
Compatibility Soluble in polar solvents (e.g., THF, DMF)

Applications

Industry Primary Uses
Spandex Fibers Lycra, elastane production
Polyurethanes TPU for footwear, automotive parts
Coatings High-performance elastomeric coatings
Adhesives Flexible sealants

Safety & Handling

Parameter Requirements
Flash Point >200°C
GHS Classification Non-hazardous
Storage Sealed, dry, 10-30°C
Shelf Life 24 months

References:

  1. Polyurethane Handbook (2nd Ed.) – G. Oertel
  2. ASTM D4274 – Polyol Hydroxyl Number

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