phthalic anhydride

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Introduction

85-44-9

C8H4O3

Applications:

Phthalic anhydride is primarily a chemical intermediate used in the manufacture of:

1. phthalate plasticizers

2. unsaturated polyester resins (UPR)

3. alkyd resins for paints and varnishes

4. polyester polyols

5. allyl resins

6. Pigments and dyes

7. Pesticide chemicals

Names and Identifiers

Name Phthalic anhydride
Synonyms AKOS BBS-00004337
anhydridephtalique
Phthalic anhydride
Anhydride phtalique
o-Phthalic anhydride
2-Benzofuran-1,3-dione
2,5-Isobenzofurandione
2-benzofuran-1,3-dione
Anhydrid kyseliny ftalove
anhydridephtalique(french)
anhydridephtalique(etatvitreux)
1,2-Benzenedicarboxylic Anhydride
2,2′-(oxydicarbonyl)dibenzoic acid
CAS 85-44-9
EINECS 201-607-5
InChI InChI=1/C16H10O7/c17-13(18)9-5-1-3-7-11(9)15(21)23-16(22)12-8-4-2-6-10(12)14(19)20/h1-8H,(H,17,18)(H,19,20)

​Physico-chemical Properties

Molecular Formula C8H4O3
Molar Mass 148.12
Density 1,53 g/cm3
Melting Point 131-134°C(lit.)
Boling Point 284°C(lit.)
Flash Point 152 °C
Water Solubility 6 g/L (20 ºC)
Solubility 6g/l (slow decomposition)
Vapor Presure <0.01 mm Hg ( 20 °C)
Vapor Density 5.1 (vs air)
Appearance Flaky Crystals
Color White
Odor Characteristic choking odor
Exposure Limit NIOSH REL: TWA 6 mg/m3 (1 ppm), IDLH 60 mg/m3; OSHA PEL: TWA 12mg/m3 (2 ppm); ACGIH TLV: TWA 1 ppm (adopted).
Merck 14,7372
BRN 118515
PH 2 (6g/l, H2O, 20℃)
Storage Condition Store below +30°C.
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong bases, moisture, strong acids. Dust may form an explosive mixture with air.
Sensitive Moisture Sensitive
Explosive Limit 1.7-10.5%(V)
Refractive Index 1.4500 (estimate)
Physical and Chemical Properties Character White needle-like crystals, with a slight odor.
melting point 131.6 ℃
boiling point 295 ℃
relative density 1.527
flash point 151.7 ℃
solubility slightly soluble in hot water and ether, soluble in ethanol, benzene and pyridine.
Use Used as analytical reagents, but also for organic synthesis

 Risk and Safety

Hazard Symbols Xn – Harmful
Risk Codes R22 – Harmful if swallowed
R37/38 – Irritating to respiratory system and skin.
R41 – Risk of serious damage to eyes
R42/43 – May cause sensitization by inhalation and skin contact.
Safety Description S23 – Do not breathe vapour.
S24/25 – Avoid contact with skin and eyes.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 – Wear suitable gloves and eye/face protection
S46 – If swallowed, seek medical advice immediately and show this container or label.
S22 – Do not breathe dust.
UN IDs 2214
WGK Germany 1
RTECS TI3150000
FLUKA BRAND F CODES 10-21
TSCA Yes
HS Code 29173500
Hazard Class 8
Packing Group III
Toxicity LD50 orally in Rabbit: 1530 mg/kg LD50 dermal Rabbit > 3160 mg/kg

Upstream Downstream Industry

Raw Materials o-Xylene
o-Xylene
Naphthalene
Downstream Products 4-Hydroxy-4-methyl-2-pentanone
Butyl ether
Anthraquinone
Tetrachlorophthalic anhydride
Tetrabromophthalic anhydride
1,4-Dihydroxyanthraquinone
2-Benzoylbenzoic acid
Phthalimide
N-(Hydroxymethyl)phthalimide
Benzanthrone
2-Ethylanthraquinone
Diallyl Phthalate

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