n-PROPYL ACETATE

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Category:Paint chemicals   Own Brand:MT  /MOQ:100KG  /From China/  B2B only.

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Introduction

Propyl acetate, also known as “n-propyl acetate” and “propyl acetate”, occurs naturally in strawberries, bananas and tomatoes. It is a product obtained by esterification of acetic acid and 1-propanol, and has the typical properties of an ester. It is a colorless transparent liquid at room temperature, and is miscible with ethanol and ether, with a special fruit flavor.

n-Propyl Acetate: Overview and Key Properties

Category Details
Chemical Name n-Propyl Acetate (Propyl Ethanoate)
Molecular Formula C₅H₁₀O₂
CAS Number 109-60-4
Appearance Colorless liquid
Odor Pleasant, fruity (pear-like)

Physical & Chemical Properties

Property Value
Boiling Point 101.6°C (214.9°F)
Melting Point −95°C (−139°F)
Density (20°C) 0.888 g/cm³
Vapor Pressure 25 mmHg (20°C)
Flash Point 14°C (57°F) – Highly flammable
Solubility Slightly soluble in water (1.9 g/100 mL); miscible with most organic solvents

Production Methods

Method Process Description
Esterification n-Propanol + Acetic Acid (acid catalyst, e.g., H₂SO₄)
Reactive Distillation Continuous process for higher efficiency

Applications

Industry Uses
Coatings & Inks Solvent for lacquers, flexographic inks
Pharmaceuticals Extraction solvent, intermediate
Food & Flavoring Artificial flavoring (pear, apple notes)
Electronics Cleaning agent for circuit boards
Adhesives Fast-evaporating solvent component

Safety & Regulatory Status

Parameter Details
OSHA PEL 200 ppm (TWA)
Health Hazards Irritant (eyes/skin); narcotic at high concentrations
Storage Keep in cool, ventilated areas away from ignition sources
Regulatory FDA-approved for food use (21 CFR 172.515)

Comparison with Similar Acetates

Acetate n-Propyl vs. Alternatives
Ethyl Acetate Higher boiling point, slower evaporation
Butyl Acetate Less pungent odor, lower solubility in water
Isopropyl Acetate Similar properties but different isomer structure

Environmental & Handling Data

Property Value
Biodegradability Readily biodegradable (OECD 301B)
LD50 (Oral, Rat) 9.370 mg/kg
VOC Status Classified as VOC (EPA)

Market Information

Aspect Details
Global Demand ~150.000 tons/year
Price Range $1.200–1.800/ton
Major Producers Dow, Eastman, BASF, Showa Denko

Key Advantages and Limitations

Advantages Limitations
Balanced evaporation rate High flammability risk
Low toxicity (vs. ketones) Moderate water solubility limits some uses
Pleasant odor for consumer applications VOC regulations may restrict use

Summary

n-Propyl Acetate is a versatile solvent prized for its fruity odor, moderate evaporation rate, and broad compatibility in coatings, inks, and flavorings. While its flammability requires careful handling, its favorable toxicity profile and biodegradability make it a preferred choice over harsher solvents. Market growth is driven by demand in eco-friendly coatings and food applications.

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