
Malononitrile CAS No.109-77-3
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Category:Agrochemicals MOQ:100KG Shipped directly from China
Introduction
Malononitrile (CAS No. 109-77-3)
1. Basic Information
- Chemical Name: Malononitrile
- Synonyms: Propanedinitrile; Dicyanomethane; Malonic dinitrile
- CAS Number: 109-77-3
- Molecular Formula: C₃H₂N₂
- Molecular Weight: 66.06 g/mol
- Appearance: White crystalline solid
- Odor: Odorless or faint aromatic odor
2. Physical and Chemical Properties
- Melting Point: 32–34 °C (90–93 °F)
- Boiling Point: 220 °C (428 °F) (decomposes)
- Density: 1.19 g/cm³ (at 20 °C)
- Solubility:
- Water: 133 g/L (20 °C)
- Organic solvents: Soluble in ethanol, acetone, ether; slightly soluble in benzene
- Vapor Pressure: 0.1 mmHg at 20 °C
- Flash Point: 112 °C (234 °F) (closed cup)
- pKa: ~11 (weakly acidic)
3. Chemical Structure
N≡C | CH₂ | C≡N
4. Hazards (GHS Classification)
- Acute Toxicity: Fatal if swallowed, inhaled, or in contact with skin (H300, H310, H330)
- Skin/Eye Irritation: Causes severe burns (H314)
- Sensitization: May cause allergic skin reaction (H317)
- Environmental Hazards: Toxic to aquatic life (H400)
- NFPA Rating: Health 3, Flammability 1, Reactivity 1
5. Storage and Handling
- Storage: Store in a cool, dry, well-ventilated area away from oxidizers and acids. Keep container tightly sealed.
- Handling: Use PPE (nitrile gloves, goggles, respirator) and work under a fume hood. Avoid dust formation.
6. Applications
- Pharmaceuticals: Intermediate for vitamins (e.g., B₁), antihypertensive drugs.
- Agrochemicals: Synthesis of pesticides and herbicides.
- Organic Synthesis: Precursor for heterocyclic compounds (e.g., pyrimidines).
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