Ion Exchanger

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Category:Chemical Additives   Own Brand:MT  /MOQ:100KG  /From China/  B2B only.

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Introduction

Ion Exchangers: Principles and Applications

1. Definition & Core Function

  • Ion exchangers are materials (resins, zeolites, or membranes) that ​selectively swap ions between a solution and a solid phase.
  • Mechanism: Reversible exchange of ions (e.g., replacing Ca²⁺ with Na⁺ in water softening).
  • Key Uses:
    • Remove undesirable ions (e.g., hardness ions, heavy metals).
    • Concentrate valuable ions (e.g., uranium recovery).
    • Purify solutions for industrial, medical, or laboratory use.

2. Types of Ion Exchangers

Type Examples Target Ions
Cation Exchangers Strong Acid (e.g., sulfonated polystyrene), Weak Acid (e.g., carboxylic resins) Ca²⁺, Mg²⁺, Fe³⁺, Pb²⁺
Anion Exchangers Strong Base (e.g., quaternary ammonium), Weak Base (e.g., amine-functionalized resins) NO₃⁻, SO₄²⁻, Cl⁻, AsO₄³⁻
Chelating Resins Iminodiacetic acid (IDA), Thiourea-based Heavy metals (Cu²⁺, Cd²⁺, Hg²⁺)
Mixed-Bed Resins Blends of cation and anion exchangers Ultra-pure water (e.g., for semiconductors)
Natural Exchangers Zeolites (clinoptilolite), Clay minerals NH₄⁺, Cs⁺, Sr²⁺ (nuclear waste)

3. Key Mechanisms

  1. Ion Exchange Process:
    • Cation Exchange
    • Anion Exchange
  2. Regeneration:
    • Cation resins regenerated with ​NaCl or ​HCl; anion resins with ​NaOH.

4. Industrial & Environmental Applications

  1. Water Softening:
    • Removes Ca²⁺/Mg²⁺ using ​strong acid cation (SAC) resins.
  2. Demineralization:
    • Produces ultra-pure water for ​power plants, pharmaceuticals (mixed-bed systems).
  3. Heavy Metal Removal:
    • Chelating resins extract Pb²⁺, Cd²⁺, or radioactive ions (e.g., Cs⁺) from wastewater.
  4. Agriculture:
    • Zeolites capture NH₄⁺ in soil, reducing fertilizer runoff.
  5. Food & Beverage:
    • Decolorize sugar syrups or remove excess minerals in brewing.
  6. Nuclear Industry:
    • Isolate radioactive isotopes (e.g., Sr-90, Cs-137) from wastewater.

5. Advantages & Limitations

Advantages Limitations
High selectivity for target ions Limited capacity (requires regeneration).
Reusable via regeneration Spent regenerant waste (e.g., brine) disposal challenges.
Cost-effective for large-scale use Slow kinetics in high-flow systems.
Eco-friendly alternatives (zeolites) Fouling by organics or suspended solids.

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