Ethanethiol CAS No. 75-08-1

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Introduction

Ethanethiol (Ethyl Mercaptan) 

CAS No.: 75-08-1 | EC No.: 200-837-3


1. Chemical Identification

Property Specification
IUPAC Name Ethane-1-thiol
Molecular Formula C₂H₅SH
Molecular Weight 62.13 g/mol
Appearance Colorless liquid
Density 0.839 g/mL at 25°C
Melting Point -148°C
Boiling Point 35°C
Refractive Index n<sup>20</sup><sub>D</sub> 1.4306
Flash Point -45°C (closed cup)
Odor Threshold 0.00019 mg/L (0.5 ppb)

Synonyms:
Ethyl mercaptan, Ethyl sulfhydrate, Mercaptoethane


2. Key Applications

Pesticide Industry
  • Organophosphate Production:
    ✓ Isopropyl phosphate
    ✓ Phorate
    ✓ Demeton (Internally absorbed phosphorus)
  • Antibacterial Agent 401 synthesis
Gas Industry
  • Odorant/Warning Agent:
    ✓ Natural gas leak detection
    ✓ LPG/propane additive
    ✓ Jet fuel odorization
Pharmaceutical Synthesis
  • Building block for sulfur-containing drug molecules

3. Product Advantages

✔ Ultra-Sensitive Odor – Reliable leak detection at 0.5 ppb
✔ High Reactivity – Effective thiolating agent
✔ Broad Utility – From agrochemicals to fuel safety


4. Physical & Chemical Properties

  • Vapor Pressure: 442 mmHg at 20°C
  • Solubility:
    • Slightly soluble in water (6.76 g/L)
    • Miscible with alcohol/ether
  • Autoignition Temp.: 299°C

5. Handling & Storage

Parameter Requirement
Storage Temp -20°C to 10°C (refrigerated)
Packaging 150kg stainless steel cylinders
Shelf Life 6 months under N₂ atmosphere
Special Notes Explosion-proof area required

6. Safety Information

Danger!

  • H220: Extremely flammable gas
  • H315+H319: Causes skin/eye irritation
  • H335: May cause respiratory irritation

Protective Measures:

  • P210: Keep away from heat/sparks/open flames
  • P377: Leaking gas fire – do not extinguish
  • P403+P233: Store in well-ventilated place

7. Quality Specifications

  • Purity: ≥98% (GC)
  • Sulfur Content: 51-53%
  • Water Content: ≤0.05%

Disclaimer:
This information is for qualified professionals only. Requires explosion-proof equipment and proper gas detection systems. Compliance with local regulations for volatile sulfur compounds is mandatory.

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