Chemical Additives

Chemical Name: Mixture of N-(1,3 – Dimethylbutyl)-N’-phenyl-p-phenylenediamine and N-(1,4 – Dimethylpentyl)-N’-phenyl-p-phenylenediamine

CAS NO.: 793-24-8,3081-01-4

Product Specification:

Appearance		Movable Black Liquid
Purity(GC),%	≥	96.0
Heat Loss(3hrs@70°C ),%	≤	0.30
Ash,%	≤	0.10
Density(45°C)		0.993-1.010
Viscosity(75°C)		70-85

◆    Performance:
– is an environment-friendly antioxidant and an outstanding antioxidant and antiozonant;
-EPPD is suitable for natural rubber and synthetic rubber and well compatible with rubber;
-EPPD is an effective stabilizer and polymerization inhibitor for solution polymerization and emulsion polymerization.

◆    Application:
-EPPD is an environment-friendly antioxidant, which can replace 8PPD;
-EPPD is mainly used as a polymerization inhibitor for the synthesis of SBR and a stabilizer for the production, storage and transportation of SBR.

◆     Packaging: Galvanized iron drum, 200kg per drum

793-24-8 – Names and Identifiers

Name	N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamine
Synonyms	BHTOX-4020 Flexzone 7F Vulkanox 4020 Santoflex6PPD Antoxidant 6ppd Antoxidant 4020 Santoflex 134PD Antioxidant 4020 N-(1,3-Dimethylbutyl Rubber Antioxidant 4020 SANTOFLEX(R) 13 PASTILLES Rubber Antioxidant 4020PPD N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamine N-(1,3-Dimethylbutyl)-N-Phenyl-1,4-Benzenediamine N-(1,3-Dimethylbutyl)-N-Phenyl-p-phenylene Diamine N-(1,3-Dimethylbutyl)-N’-phenyl-p-phenylenediamine N-(1.3-dimethylbutyl)-N’-phenyl-p-phenylenediamine N-(4-methylpentan-2-yl)-N’-phenylbenzene-1,4-diamine 1,4-BenzenediaMine,N1-(1,3-diMethylbutyl)-N4-phenyl- N1-(4-methylpentan-2-yl)-N4-phenyl-benzene-1,4-diamine 1-N-(4-methylpentan-2-yl)-4-N-phenylbenzene-1,4-diamine 4020,N-(1,3-DiMethylbutyl)-N’-phenyl-p-phenylenediaMine
CAS	793-24-8
EINECS	212-344-0
InChI	InChI=1/C18H24N2/c1-14(2)13-15(3)19-17-9-11-18(12-10-17)20-16-7-5-4-6-8-16/h4-12,14-15,19-20H,13H2,1-3H3
InChIKey	ZZMVLMVFYMGSMY-UHFFFAOYSA-N

793-24-8 – Physico-chemical Properties

Molecular Formula	C18H24N2
Molar Mass	268.4
Density	0.986~1.00g/cm3
Melting Point	45-46°C
Boling Point	260°C
Flash Point	204°C
Water Solubility	<0.1 g/100 mL at 17 ºC
Solubility	soluble in Methanol
Vapor Presure	5.22E-07mmHg at 25°C
Appearance	Dark brown black solid
Color	Light orange to Dark red to Black
pKa	6.73±0.32(Predicted)
Storage Condition	Keep in dark place,Sealed in dry,Room Temperature
Refractive Index	1.6300 (estimate)
MDL	MFCD00072248
Physical and Chemical Properties	Gray-black solid.
Use	Natural rubber and synthetic rubber with anti-ozone agent and antioxidant, ozone crack and flex fatigue excellent protective effect

793-24-8 – Risk and Safety

Risk Codes	R22 – Harmful if swallowed R43 – May cause sensitization by skin contact R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Description	S36/37 – Wear suitable protective clothing and gloves. S60 – This material and its container must be disposed of as hazardous waste. S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
UN IDs	UN 3077 9 / PGIII
WGK Germany	2
RTECS	ST0900000
HS Code	29215190
Hazard Class	9
Packing Group	III
Toxicity	LD50 oral in rat: 3580mg/kg

3081-01-4 – Names and Identifiers

Name	N-(1,4-dimethylpentyl)-N’-phenylbenzene-1,4-diamine
Synonyms	Einecs 221-374-3 SANTOFLEX14ANTIOZONANT N14DIMETHYLPENTYLNPHENYL14BENZENEDIAMINE N-(1,4-Dimethylamyl)-N’-phenyl-p-phenylenediamine N-(1,4-dimethylpentyl)-N’-phenylbenzene-1,4-diamine N-(1,4-dimethylpentyl)-N’-phenyl-p-phenylenediamine 1,4-Benzenediamine, N-(1,4-dimethylpentyl)-N-phenyl- 1,4-Benzenediamine, N1-(1,4-dimethylpentyl)-N4-phenyl-
CAS	3081-01-4
EINECS	221-374-3

3081-01-4 – Physico-chemical Properties

Molecular Formula	C19H26N2
Molar Mass	282.42
Density	0.9517 (rough estimate)
Boling Point	415.03°C (rough estimate)
Water Solubility	670μg/L at 25℃
Vapor Presure	0Pa at 25℃
pKa	6.70±0.50(Predicted)
Refractive Index	1.8676 (estimate)

3081-01-4 – References

LogP	5.17 at 20℃

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