Benzoic Acid

Names and Identifiers Name Benzoic acid Synonyms 210 benzoate a 1 (acid) Benzyl acid Benzoic acid SS Benzoic Acid Acide benzoique 4-Carboxypolystyrene Benzoic acid, USP Grade Benzoic aBenzoic ...

Category:Food Additives

Introduction

Names and Identifiers

Name Benzoic acid
Synonyms 210
benzoate
a 1 (acid)
Benzyl acid
Benzoic acid
SS Benzoic Acid
Acide benzoique
4-Carboxypolystyrene
Benzoic acid, USP Grade
Benzoic aBenzoic acidcid
Mefenamic Acid Impurity D
Industrial-use benzoic acid
Benzoic-12C7 acid, 13C-depleted
Melting point standard benzoic acid
Glycopyrronium Bromide EP Impurity D
CAS 65-85-0
EINECS 200-618-2
InChI InChI=1/C7H6O2/c8-7(9)6-4-2-1-3-5-6/h1-5H,(H,8,9)/p-1
InChIKey WPYMKLBDIGXBTP-UHFFFAOYSA-N

Physico-chemical Properties

Molecular Formula C7H6O2
Molar Mass 122.12
Density 1.08
Melting Point 121-125°C(lit.)
Boling Point 249°C(lit.)
Flash Point 250°F
JECFA Number 850
Water Solubility Slightly soluble. 0.34 g/100 mL
Solubility Slightly soluble in water, soluble in ethanol, methanol, ether, chloroform, benzene, toluene, carbon disulfide, carbon tetrachloride and turpentine.
Vapor Presure 10 mm Hg ( 132 °C)
Vapor Density 4.21 (vs air)
Appearance White crystalline powder
Color White to yellow-beige to orange
Merck 14,1091
BRN 636131
pKa 4.19(at 25℃)
PH 3.66(1 mM solution);3.12(10 mM solution);2.6(100 mM solution);
Storage Condition 2-8°C
Stability Stable. Combustible. Incompatible with strong bases, strong oxidizing agents, alkalies.
Sensitive Easily absorbing moisture
Refractive Index 1.504
MDL MFCD00002398
Physical and Chemical Properties Scaly or needle-like crystals. Has the odor of benzene or formaldehyde.
slightly soluble in water, soluble in ethanol, methanol, ether, chloroform, benzene, toluene, carbon disulfide, carbon tetrachloride and turpentine.
Use It is used in the production of medicines, dye carriers, plasticizers, spices and food preservatives, and also used in the performance improvement of alkyd resin coatings; It is used as an intermediate for pharmaceuticals and dyes, and is used in the preparation of plasticizers and perfumes, etc, also as a rust inhibitor for iron and steel equipment

Risk and Safety

Risk Codes R22 – Harmful if swallowed
R36 – Irritating to the eyes
R42/43 – May cause sensitization by inhalation and skin contact.
R36/37/38 – Irritating to eyes, respiratory system and skin.
R40 – Limited evidence of a carcinogenic effect
R63 – Possible risk of harm to the unborn child
R43 – May cause sensitization by skin contact
R23/24/25 – Toxic by inhalation, in contact with skin and if swallowed.
R45 – May cause cancer
R41 – Risk of serious damage to eyes
R37/38 – Irritating to respiratory system and skin.
R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed.
R48/23 –
R38 – Irritating to the skin
R67 – Vapors may cause drowsiness and dizziness
R37 – Irritating to the respiratory system
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S37/39 – Wear suitable gloves and eye/face protection
S24 – Avoid contact with skin.
S22 – Do not breathe dust.
S36/37 – Wear suitable protective clothing and gloves.
S24/25 – Avoid contact with skin and eyes.
S23 – Do not breathe vapour.
S53 – Avoid exposure – obtain special instructions before use.
S36 – Wear suitable protective clothing.
S63 –
S39 – Wear eye / face protection.
UN IDs UN 3077 9/PG 3
WGK Germany 1
RTECS DG0875000
FLUKA BRAND F CODES 21
TSCA Yes
HS Code 2916 31 00
Hazard Note Harmful
Toxicity LD50 orally in Rabbit: 1700 mg/kg LD50 dermal Rabbit > 5000 mg/kg

Product name:

Benzoic Acid

It is used in the preservatives production of pharmaceuticals, dye carriers, plasticizers, perfumes and food, as well as in the performance improvement of alkyd resin coatings; as an intermediate in pharmaceuticals and dyes for the preparation of plasticizers and spices, etc.

Description

It is a white or almost white, crystalline powder or colourless crystals. It is slightly soluble in water, soluble in boiling water, freely soluble in ethanol (96 per cent) and in fatty oils.

Application

It is a preservative primarily for use against molds and yeasts, white crystals or powder, commonly used in food industry. In acidic condition, it has inhibitory effect, the optimum pH value is 2.5-4.0. Benzoic acid is used in concentrations of 0.05 to 0.1 percent. Due to the low solubility of benzoic acid and use shall be stirring, or dissolved in a small amount of hot water or ethanol, it is often used in the sodium salt.

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