Acenaphthene

Pharmaceutical Materials 2025-03-02

CAS Number: 83-32-9

Molecular Formula: C12H10

Molecular Weight: 154.21

Appearance: White needles or crystalline powder

Melting Point: 90-94°C

Boiling Point: 279°C

Usage: Mainly used as a dye intermediate.

 

Attribute Details
Chemical Name Acenaphthene
CAS Number 83-32-9
Synonyms 1.2-Dihydroacenaphthylene; Acenaphthylene, 1.2-dihydro-; Acenaphthene, 1.8-ethylenenaphthalene; Dihydroacenaphthene; Naphthacene, 1.2.3.4.4a,5.6.7-octahydro-1.4a-dimethyl-
Molecular Formula C12H10
Molecular Weight 154.21 g/mol
Appearance White needle-like crystals
Physical Properties Melting Point: 93-94°C; Boiling Point: 279°C; Density: 1.024 g/cm³ (at 20°C); Flash Point: 120°C; Solubility: Insoluble in water, slightly soluble in ethanol, soluble in chloroform, benzene, toluene, glacial acetic acid, and petroleum ether
Chemical Properties Undergoes Birch reduction to form 2a,3-acenaphthylene. Oxidation with potassium permanganate yields 1.8-naphthalic anhydride. Electrophilic substitution mainly occurs at the 5-position, such as bromination, nitration, and alkylation.
Main Uses Used as an intermediate in the production of dyes, pesticides, and pharmaceuticals. Also employed in the synthesis of polyester resins, polyester fibers, and fluorescent pigments.
Safety Information Considered a toxic substance. May cause irritation to eyes, skin, and respiratory tract. Handle with caution, avoiding contact with oxidants. Store in a cool, dry place, away from heat and sources of ignition.
Production Method Primarily extracted from coal tar. Obtained by fractional distillation of coal tar wash oil, followed by further purification.

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