2,3-Dichloropropene

Agrochemicals 2025-03-02

2,3-Dichloropropene

Chemical Name: 2,3-Dichloroprop-1-ene
Synonyms: 2,3-Dichloropropylene; DCP
CAS Number: 78-88-6
Molecular Formula: C₃H₄Cl₂
Molecular Weight: 110.97 g/mol


Physical & Chemical Properties

Property Value
Appearance Colorless to pale yellow liquid
Odor Pungent, chloroform-like
Melting Point -80°C (-112°F)
Boiling Point 94-96°C (201-205°F)
Density 1.224 g/cm³ (20°C)
Vapor Pressure 40 mmHg (20°C)
Flash Point 16°C (61°F) (Flammable)
Solubility Insoluble in water; miscible with organic solvents

Hazard & Safety Information (GHS)

Danger Symbols:
🔥 Flammable (F)
☠️ Toxic (T)
⚠️ Irritant (Xi)

Hazard Codes:
• H225: Highly flammable liquid and vapor
• H301: Toxic if swallowed
• H315: Causes skin irritation
• H319: Causes serious eye irritation
• H335: May cause respiratory irritation
• H411: Toxic to aquatic life

Protective Measures:
• P210: Keep away from heat/sparks/open flames
• P280: Wear gloves/eye protection
• P301+P310: IF SWALLOWED: Call poison center immediately
• P303+P361+P353: IF ON SKIN: Remove clothing, rinse skin


Chemical Behavior

• Reactivity:

  • Polymerizes explosively with strong acids or metals (e.g., aluminum)
  • Forms toxic gases (HCl, phosgene) when heated
    • Stability:
  • Stabilized with 0.1% epichlorohydrin or amines
  • Light-sensitive (store in amber bottles)

Applications

✔ Intermediate for pesticides (e.g., DDVP)
✔ Organic synthesis (alkylating agent)
✔ Former fumigant (now restricted)

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