Hydrocarbons

Organic Chemicals 2025-03-02

Definition & Composition

Hydrocarbons are organic compounds composed exclusively of hydrogen (H) and carbon (C) atoms.

  • General Formula: CₓHᵧ
  • Key Feature: Nonpolar, hydrophobic, and combustible.

Classification & Examples

Category Structure Example Compounds Properties
Alkanes (Paraffins) C–C single bonds Methane (CH₄), Octane (C₈H₁₈) Saturated, low reactivity
Alkenes (Olefins) C=C double bonds Ethylene (C₂H₄), Propylene (C₃H₆) Unsaturated, polymerization
Alkynes C≡C triple bonds Acetylene (C₂H₂) Highly reactive, welding fuel
Aromatics Benzene rings (C₆H₆) Toluene, Xylene Stable, carcinogenic potential

Key Properties

Property Alkanes Alkenes/Alkynes Aromatics
Reactivity Low (free radical) High (electrophilic) Moderate (substitution)
Boiling Point Increases with chain length Similar trend Higher due to ring structure
Combustion Clean flame (CH₄) Sooty flame (C₂H₂) Smoky flame (C₆H₆)

Natural Sources & Extraction

Source Hydrocarbon Type Extraction Method
Natural Gas Methane (CH₄) Drilling, fracking
Crude Oil C5–C40 alkanes Fractional distillation
Coal Aromatics (e.g., benzene) Destructive distillation

Industrial Applications

Industry Use Case Example Hydrocarbon
Energy Gasoline, jet fuel Octane (C₈H₁₈)
Polymers Plastics (PE, PP, PVC) Ethylene (C₂H₄)
Chemicals Solvents, synthetic rubbers Butadiene (C₄H₆)
Pharmaceuticals Drug precursors (e.g., aspirin) Toluene (C₇H₈)

Environmental Impact

Issue Cause Mitigation
CO₂ Emissions Combustion of fossil fuels Carbon capture (CCS)
Air Pollution Incomplete combustion (CO, soot) Catalytic converters
Spills Oil leaks/accidents Bioremediation

Safety & Handling

Hazard Precaution Example
Flammability Store in flame-proof areas Gasoline (Flash point: -43°C)
Toxicity Ventilation for volatile aromatics Benzene (carcinogen)
Asphyxiation Monitor methane leaks Natural gas (odorless)

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