Dimethyl carbonate CAS No.616-38-6

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Introduction

Dimethyl Carbonate (CAS No. 616-38-6) 

1. Basic Information

  • Chemical Name: Dimethyl Carbonate
  • Synonyms: DMC; Methyl carbonate; Carbonic acid dimethyl ester
  • CAS Number: 616-38-6
  • Molecular Formula: C₃H₆O₃
  • Molecular Weight: 90.08 g/mol
  • Appearance: Colorless liquid
  • Odor: Mild, ester-like odor

2. Physical and Chemical Properties

  • Melting Point: 2–4 °C (36–39 °F)
  • Boiling Point: 90 °C (194 °F)
  • Density: 1.07 g/cm³ (at 20 °C)
  • Solubility:
    • Water: Slightly soluble (13 g/L at 20 °C)
    • Organic solvents: Miscible with alcohols, ethers, benzene
  • Refractive Index: 1.368–1.369 (20 °C)
  • Flash Point: 17 °C (63 °F) (closed cup) – Highly Flammable
  • Vapor Pressure: 62 mmHg at 20 °C

3. Chemical Structure

    O  
   ║  
CH₃-O-C-O-CH₃

4. Hazards (GHS Classification)

  • Flammability: Highly flammable liquid (H225)
  • Health Hazards:
    • Eye/Irritation: Causes mild irritation (H319)
    • Inhalation: May cause dizziness or respiratory tract irritation (H336)
  • Environmental Hazards: Low toxicity to aquatic life (H402)
  • NFPA Rating: Health 1, Flammability 3, Reactivity 0

5. Storage and Handling

  • Storage: Store in a cool, well-ventilated area away from heat/sparks/open flames. Use explosion-proof equipment.
  • Handling: Use PPE (gloves, goggles, vapor respirator) and ground containers to prevent static discharge.

6. Applications

  • Green Solvent: Replacement for toxic solvents (e.g., MTBE, DCM) in coatings, adhesives.
  • Chemical Synthesis: Methylating/ carbonylating agent in pharmaceuticals (e.g., pesticides, polycarbonates).
  • Electrolytes: Used in lithium-ion batteries.

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