PHENOLIC RESIN

Phenolic resin is the reaction product of phenol and formaldehyde. It offers good mechanical strength, dimensional/thermal stability, and good resistance to electricity, solvent, and acid. It is wi...

Category:Paint chemicals

Introduction

Phenolic resin is the reaction product of phenol and formaldehyde. It offers good mechanical strength, dimensional/thermal stability, and good resistance to electricity, solvent, and acid. It is widely used in molding materials (including electronic packaging materials), laminating materials, polishing materials, bonding, impregnation, casting and other applications.

Phenolic Resin: Overview and Key Properties

Category Details
Chemical Name Phenol-formaldehyde resin (PF)
Type Thermosetting polymer
Discovery First synthesized by Leo Baekeland (1907)
Monomer Units Phenol (C₆H₅OH) + Formaldehyde (CH₂O)
Curing Process Heat-induced cross-linking (irreversible)

Types of Phenolic Resins

Type Characteristics Applications
Resole Resin Alkaline-catalyzed, heat-curable; soluble in alcohols Adhesives, coatings, laminates
Novolac Resin Acid-catalyzed, requires curing agents (e.g., hexamine) Molding compounds, abrasives

Properties

Property Value/Description
Thermal Stability Up to 300°C (572°F)
Flame Resistance Self-extinguishing, low smoke
Electrical Insulation Excellent dielectric properties
Chemical Resistance Resistant to acids, solvents
Mechanical Strength High rigidity, brittle without fillers

Applications

Industry Uses
Automotive Brake linings, clutch plates
Electronics Circuit boards, insulation parts
Construction Plywood adhesives, laminates
Consumer Goods Kitchenware handles, billiard balls

Advantages vs. Limitations

Advantages Limitations
High heat resistance Brittleness (requires additives)
Low cost Dark color (limited to opaque uses)
Eco-friendly (no halogens) Slow curing time

Comparison with Other Resins

Resin Type Phenolic vs. Others
Epoxy Lower cost, but weaker adhesion
Polyester Less heat-resistant, more flexible
Silicone Higher temperature tolerance, more expensive

Summary

Phenolic resin, the first synthetic polymer, remains vital due to its thermal stability, flame resistance, and cost-effectiveness. Though brittle, its versatility spans adhesives, electronics, and fire-safe components. Innovations focus on enhancing toughness and expanding applications in green composites.

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