dodecylamine
CAS No. 124-22-1
Content 98%
Packing 160kg/drum
Names and Identifiers
Name
Dodecylamine
Synonyms
A12
Laurylamine
Dodecylamine
Dodecanamine
1-Dideanamine
1-Aminododecan
1-Aminododecane
dodecan-...
Category：Paint chemicals
Introduction
CAS No. 124-22-1
Content 98%
Packing 160kg/drum
Names and Identifiers
| Name | Dodecylamine |
| Synonyms | A12 Laurylamine Dodecylamine Dodecanamine 1-Dideanamine 1-Aminododecan 1-Aminododecane dodecan-1-amine DODECYLAMINE pure dodecan-1-aminium chloride Dodecylamine,1-Aminododecane, Laurylamine 1-Aminododecane Laurylamine 1-Dodecanamine Dodecan-1-amine, 1-Aminododecane, Laurylamine |
| CAS | 124-22-1 |
| EINECS | 204-690-6 |
| InChI | InChI=1/C12H27N.H2O4S/c1-2-3-4-5-6-7-8-9-10-11-12-13;1-5(2,3)4/h2-13H2,1H3;(H2,1,2,3,4) |
| InChIKey | JRBPAEWTRLWTQC-UHFFFAOYSA-N |
Physico-chemical Properties
| Molecular Formula | C12H27N |
| Molar Mass | 185.35 |
| Density | 0.806g/mLat 25°C(lit.) |
| Melting Point | 27-29°C(lit.) |
| Boling Point | 247-249°C(lit.) |
| Flash Point | >230°F |
| Water Solubility | 78 mg/L (25 ºC) |
| Solubility | water: soluble3.5g/L at 25°C |
| Vapor Presure | 64 mm Hg ( 170 °C) |
| Appearance | Crystalline Low Melting Solid |
| Specific Gravity | 0.806 |
| Color | White |
| BRN | 1633576 |
| pKa | 10.63(at 25℃) |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Combustible. Incompatible with acid chlorides, acids, acid anhydrides, oxidizing agents. |
| Refractive Index | 1.4421 |
| Physical and Chemical Properties | White waxy solid. Specific gravity (4 ℃):0.79 density (g/ml,20 ℃):0.78 boiling point (℃):212.63 color (APHA)Max:30 flash point (℃):<72.50 used in the production of pharmaceuticals, pesticides, dyes, mineral flotation agents, emulsifiers and fine chemicals intermediates. |
| Use | For the preparation of surfactants, mineral flotation agent, dodecyl quaternary ammonium salt, fungicides, pesticides, emulsifiers, detergents |
Risk and Safety
| Risk Codes | R22 – Harmful if swallowed R34 – Causes burns R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R20/21/22 – Harmful by inhalation, in contact with skin and if swallowed. R65 – Harmful: May cause lung damage if swallowed R48/22 – Harmful danger of serious damage to health by prolonged exposure if swallowed. R37 – Irritating to the respiratory system R35 – Causes severe burns |
| Safety Description | S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection. S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 – This material and its container must be disposed of as hazardous waste. S61 – Avoid release to the environment. Refer to special instructions / safety data sheets. S62 – If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label. |
| UN IDs | UN 3259 8/PG 3 |
| WGK Germany | 2 |
| RTECS | JR6475000 |
| FLUKA BRAND F CODES | 10-34 |
| TSCA | Yes |
| HS Code | 29211980 |
| Hazard Class | 8 |
| Packing Group | II |
| Toxicity | LD50 orally in Rabbit: 1020 mg/kg |
Reference Information
| LogP | 4.33 at 25℃ |
| Introduction | dodecylprimary amines, also known as 1-aminododecane, laurylamine, dodecylamine, colorless or white crystals. This product is weak alkaline, and inorganic acid or organic acid can generate salt. Quaternary ammonium salt may be used. With the epoxy ring reaction, can be acetylated. With unsaturated hydrocarbons can be added. Peroxide can be used to oxidize this product. The reaction with a halogenated carboxylic acid produces an amphoteric compound. Reaction with carboxylic acid chloride, can produce amide. The Mannish reaction with the nucleophile or phenol can be carried out to produce a polyfunctional species. With hydrochloric acid, the formation of hydrochloric acid dodecylamine. |
| Application | dodecylprimary amine is an important intermediate for the synthesis of cationic and zwitterionic surfactants, which is widely used in mineral flotation agent, fiber waterproof softener, dyeing auxiliaries, antistatic agents, pigment dispersants, anti-rust agents, chemical fertilizer anti-caking agents, lubricating oil additives, sterilization disinfectants, etc. |
| toxicological data | 1. Skin/eye irritation: rabbit skin standard Drez-eye test: 750ug/24h has serious irritation to the skin. Rabbit eye standard Drez-eye test: 50ug/24h had severe eye irritation. 2. Acute toxicity: Rat oral LD5O:1020mg/kg; Mouse oral LD5O:1160mg/kg; Mouse peritoneal LD5O:50mg/kg |
| purpose | for the preparation of surfactants, mineral flotation agents, dodecyl quaternary ammonium salts, fungicides, pesticides, emulsifiers, detergent and other organic synthesis intermediates, used in textile and rubber and other additives production. It can also be used to prepare Ore flotation agent, dodecyl quaternary ammonium salt, bactericide, insecticide, emulsifier, detergent and Disinfection special effect agent for prevention and treatment of skin burn and curing. used as an active agent in geological analysis and also in chromatographic analysis organic synthesis. |
| production method | with lauric acid as raw material, ammonia gas is introduced into the reaction in the presence of silica gel as catalyst, and the product is washed with water, dried, distillation under reduced pressure gave lauronitrile. Lauronitrile is hydrogenated under active nickel catalysis, I .e., it is reduced to give dodecylamine. Lauronitrile was added to the autoclave, and an appropriate amount of active nickel was added to replace the room air with nitrogen. The mixture was heated to 80 ° C. With stirring, and hydrogen charging was repeated until absorption was no longer observed, and the reaction was maintained for 3 hours. After cooling, the obtained crude product was subjected to distillation under reduced pressure to obtain dodecylamine. |
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